Department of Earth Sciences, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo 169-8050, Japan.
Graduate School of Creative Science and Engineering, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo 169-8050, Japan.
J Colloid Interface Sci. 2014 Apr 15;420:66-9. doi: 10.1016/j.jcis.2014.01.002. Epub 2014 Jan 13.
Well-defined plate and hollow disk of silica-dioctadecyldimethylammonium hybrid particles were obtained by the sol-gel reaction of tetraethoxysilane in the presence of dioctadecyldimethylammonium chloride, where synthetic condition was determined based on the Stöber synthesis for micron size silica sphere. The particle size was several hundreds of nm in the radius and several tens of nm in the thickness. X-ray powder diffraction patterns indicated that the products possess layered mesostructures, which were thought to be directed by the lamellar aggregates of dioctadecyldimethylammonium.
通过在氯化二辛基二甲基铵存在下的四乙氧基硅烷的溶胶-凝胶反应,得到了具有明确的硅-二辛基二甲基铵混合颗粒的板和中空盘。其中,合成条件是基于微米尺寸的硅球的 Stöber 合成来确定的。颗粒的半径为几百纳米,厚度为几十纳米。X 射线粉末衍射图谱表明,产物具有层状介孔结构,这被认为是由二辛基二甲基铵的层状聚集体引导的。