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通过分离层间缩合和有机客体分子消除的形成阶段,将层状八硅酸盐最佳拓扑转化为RWR型沸石。

Optimal topotactic conversion of layered octosilicate to RWR-type zeolite by separating the formation stages of interlayer condensation and elimination of organic guest molecules.

作者信息

Asakura Yusuke, Osada Shimon, Hosaka Nami, Terasawa Taichi, Kuroda Kazuyuki

机构信息

Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo, 169-8555, Japan.

出版信息

Dalton Trans. 2014 Jul 21;43(27):10392-5. doi: 10.1039/c3dt53533a. Epub 2014 Feb 24.

Abstract

We demonstrate that the separation of two stages of interlayer condensation under refluxing and elimination of organic guests provides the optimal conditions for the formation of RWR-type zeolite from layered octosilicate. The obtained RWR-type zeolite has higher quality than any other RWR-type zeolite reported previously.

摘要

我们证明,在回流和去除有机客体的条件下,层间缩合的两个阶段的分离为从层状八硅酸盐形成RWR型沸石提供了最佳条件。所获得的RWR型沸石的质量高于先前报道的任何其他RWR型沸石。

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