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由光致变色2-噻吩基型二芳基乙烯组成的表面受限自组装的光触发形成与消失:液/固界面处的协同模型

Phototriggered formation and disappearance of surface-confined self-assembly composed of photochromic 2-thienyl-type diarylethene: a cooperative model at the liquid/solid interface.

作者信息

Yokoyama Soichi, Hirose Takashi, Matsuda Kenji

机构信息

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Chem Commun (Camb). 2014 Jun 7;50(45):5964-6. doi: 10.1039/c3cc48895k.

DOI:10.1039/c3cc48895k
PMID:24575425
Abstract

A photoresponsive self-assembly on a 2-D surface was investigated by scanning tunnelling microscopy (STM). The open-ring isomer of a diarylethene derivative showed an abrupt ordering formation at a critical concentration, which was successfully reproduced by a cooperative model based on Langmuir-type adsorption.

摘要

通过扫描隧道显微镜(STM)研究了二维表面上的光响应自组装。二芳基乙烯衍生物的开环异构体在临界浓度下显示出突然的有序形成,这通过基于朗缪尔型吸附的协同模型成功再现。

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