Yokoyama Soichi, Hirose Takashi, Matsuda Kenji
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Chem Commun (Camb). 2014 Jun 7;50(45):5964-6. doi: 10.1039/c3cc48895k.
A photoresponsive self-assembly on a 2-D surface was investigated by scanning tunnelling microscopy (STM). The open-ring isomer of a diarylethene derivative showed an abrupt ordering formation at a critical concentration, which was successfully reproduced by a cooperative model based on Langmuir-type adsorption.
通过扫描隧道显微镜(STM)研究了二维表面上的光响应自组装。二芳基乙烯衍生物的开环异构体在临界浓度下显示出突然的有序形成,这通过基于朗缪尔型吸附的协同模型成功再现。