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手性联萘胺衍生物的高对映选择性动力学拆分,由布朗斯台德酸催化。

Highly enantioselective kinetic resolution of axially chiral BINAM derivatives catalyzed by a Brønsted acid.

机构信息

Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China).

出版信息

Angew Chem Int Ed Engl. 2014 Apr 1;53(14):3684-7. doi: 10.1002/anie.201310562. Epub 2014 Mar 3.

Abstract

A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Brønsted acid-catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities.

摘要

发展了一种高效的动力学拆分轴手性 BINAM 衍生物的策略,涉及手性 Brønsted 酸催化的亚胺形成和转移氢化级联反应。动力学拆分以高产率和优异的对映选择性为手性 BINAM 衍生物提供了一条方便的途径。

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