Wang Yingying, Liu Fuguo, Liang Chunxuan, Yuan Fang, Gao Yanxiang
Beijing Key Laboratory of Functional Food from Plant Resources, College of Food Science & Nutritional Engineering, China Agricultural University, Beijing, 100083, China.
J Sci Food Agric. 2014 Nov;94(14):2986-91. doi: 10.1002/jsfa.6644. Epub 2014 Apr 4.
Edible films based on Maillard reaction products (MRPs) of ε-polylysine and chitosan, without the use of any plasticiser, were prepared by solution casting. The effect of Maillard reaction parameters (reaction time and the ratio of polylysine/chitosan) of ε-polylysine and chitosan on the structure, moisture content, water solubility, total colour difference and mechanical properties of edible films formed by MRPs were systematically evaluated.
Scanning electron microscopy confirmed that edible films prepared by the MRPs of ε-polylysine and chitosan through the Maillard reaction exhibited a more compact and dense structure than those from the mixture of biopolymers without the presence of MRPs. The tensile strength and % elongation values of films from the mixture were decreased significantly with the rise of ε-polylysine (P < 0.05). The moisture content of the films was not significantly affected by Maillard reaction, whereas water solubility was decreased and total colour difference was increased significantly (P < 0.05) with the extension of Maillard reaction time. In addition, antimicrobial activity of chitosan films against E. coli and S. aureus. could be achieved by incorporating ε-polylysine into chitosan.
These films can ensure food quality and safety, especially for coating highly perishable foods, such as meat products. © 2014 Society of Chemical Industry.
通过溶液浇铸法制备了基于ε-聚赖氨酸和壳聚糖的美拉德反应产物(MRPs)的可食用薄膜,且未使用任何增塑剂。系统评估了ε-聚赖氨酸和壳聚糖的美拉德反应参数(反应时间和聚赖氨酸/壳聚糖比例)对由MRPs形成的可食用薄膜的结构、水分含量、水溶性、总色差和机械性能的影响。
扫描电子显微镜证实,通过美拉德反应由ε-聚赖氨酸和壳聚糖的MRPs制备的可食用薄膜比没有MRPs存在时由生物聚合物混合物制备的薄膜具有更致密的结构。随着ε-聚赖氨酸含量的增加,混合物薄膜的拉伸强度和伸长率值显著降低(P<0.05)。美拉德反应对薄膜的水分含量没有显著影响,然而,随着美拉德反应时间的延长,水溶性降低,总色差显著增加(P<0.05)。此外,通过将ε-聚赖氨酸掺入壳聚糖中,可以实现壳聚糖薄膜对大肠杆菌和金黄色葡萄球菌的抗菌活性。
这些薄膜可以确保食品质量和安全,特别是用于涂覆高度易腐食品,如肉制品。©2014化学工业协会。