Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133 Rome, Italy.
Chem Commun (Camb). 2014 Apr 21;50(31):4076-8. doi: 10.1039/c3cc49416k.
Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.
已经确定了两种合成路线来制备 5,10,15-三(三氟甲基)取代卟啉铜衍生物。该配合物已被表征，初步电化学研究表明卟啉和中位二茂铁取代基之间存在强烈相互作用。所得结果表明，通过将二茂铁取代基的偏心特性与卟啉大环相结合，可以获得特殊的性质。
