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柠檬酸杆菌O23-脂多糖O-特异性多糖链的结构

The structure of the O-specific polysaccharide chain from Citrobacter O23-lipopolysaccharide.

作者信息

Katzenellenbogen E, Ekiel I, Romanowska E

机构信息

Department of Immunochemistry, Polish Academy of Sciences, Wrocław.

出版信息

Carbohydr Res. 1988 Aug 15;179:349-57. doi: 10.1016/0008-6215(88)84131-4.

Abstract

The structure of Citrobacter O23-specific polysaccharide has been shown by sugar and methylation analyses of the native and chemically degraded polysaccharide and by 1H- and 13C-n.m.r. spectroscopy to consist of the tetrasaccharide repeating-units: ----4)-alpha-D-Man-(1----2)-alpha-D-Man-(1----2)-beta-D-Man- (1----3)-alpha-D-GalNAc-(1----, 80% of which are substituted by O-acetyl groups.

摘要

通过对天然和化学降解多糖的糖分析、甲基化分析以及1H和13C核磁共振光谱分析表明,柠檬酸杆菌O23特异性多糖的结构由四糖重复单元组成:----4)-α-D-甘露糖-(1----2)-α-D-甘露糖-(1----2)-β-D-甘露糖-(1----3)-α-D-N-乙酰半乳糖胺-(1----,其中80%被O-乙酰基取代。

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