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基于气相色谱-质谱联用仪的食用油挥发性有机化合物化学成分研究

[Study on the chemical compositions of VOCs emitted by cooking oils based on GC-MS].

作者信息

He Wan-Qing, Nie Lei, Tian Gang, Li Jing, Shao Xia, Wang Min-Yan

出版信息

Huan Jing Ke Xue. 2013 Dec;34(12):4605-11.

Abstract

Volatile organic compounds (VOCs) are key precursors of ozone and secondary organic aerosols in air, and the differences in the compositions of VOCs lead to their different contribution to atmospheric reaction. Cooking oil fume is one of the important sources of atmospheric VOCs, and its chemical compositions are distinct under different conditions of oil types, food types, cooking methods and heating temperatures etc. In this study, the production of cooking oil fume was simulated by heating typical pure vegetable oils (peanut oil, sunflower oil, soybean oil, olive oil and blend oil) at different temperatures in beakers to investigate the chemical compositions of VOCs. The emitted VOCs were sampled with a Tenax adsorption tube and analyzed using GC-MS after thermal desorption. According to spectral library search and map analysis, using area normalized semi-quantitative method, preliminary qualitative and quantitative tests were conducted for the specific components of VOCs under different conditions.

摘要

挥发性有机化合物(VOCs)是空气中臭氧和二次有机气溶胶的关键前体物,VOCs组成的差异导致其对大气反应的贡献不同。食用油油烟是大气VOCs的重要来源之一,其化学成分在油的种类、食物种类、烹饪方法和加热温度等不同条件下各不相同。在本研究中,通过在烧杯中对典型的纯植物油(花生油、向日葵油、大豆油、橄榄油和调和油)在不同温度下加热来模拟食用油油烟的产生,以研究VOCs的化学成分。用Tenax吸附管采集排放的VOCs,并在热解吸后用气相色谱-质谱联用仪进行分析。根据谱库检索和图谱分析,采用面积归一化半定量方法,对不同条件下VOCs的特定成分进行了初步定性和定量检测。

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