Department of Electrical and Computer Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo , Waterloo, Ontario N2L 3G1, Canada.
ACS Nano. 2014 Apr 22;8(4):3483-9. doi: 10.1021/nn4064659. Epub 2014 Apr 2.
An electron beam resist is typically applied by spin-coating, which cannot be reliably applied on nonplanar, irregular, or fragile substrates. Here we demonstrate that the popular negative electron beam resist polystyrene can be coated by thermal evaporation. A high resolution of 30 nm half-pitch was achieved using the evaporated resist. As a proof of concept of patterning on irregular surfaces, we fabricated nanostructures on the AFM cantilever and the optical fiber. Although an ice (H2O) resist has also been recently demonstrated as being capable of nanopatterning on irregular and fragile substrates, it requires specially designed accessories mounted inside a SEM chamber, whereas our process works with any thermal evaporator and is thus simpler and much more accessible. Nanofabrication on nonplanar surfaces may find applications in fields such as (AFM) tip-enhanced Raman spectroscopy for chemical analysis and lab-on-fiber technology.
电子束抗蚀剂通常通过旋涂来施加,但在非平面、不规则或易碎的衬底上无法可靠地应用。在这里,我们证明了流行的负电子束抗蚀剂聚苯乙烯可以通过热蒸发来涂覆。使用蒸发的抗蚀剂实现了 30nm 半间距的高分辨率。作为在不规则表面上进行图案化的概念验证,我们在 AFM 悬臂和光纤上制造了纳米结构。尽管最近也证明了冰(H2O)抗蚀剂能够在不规则和易碎的衬底上进行纳米图案化,但它需要专门设计的附件安装在 SEM 室内,而我们的工艺适用于任何热蒸发器,因此更简单,更易于使用。非平面表面上的纳米制造可能在(AFM)针尖增强拉曼光谱化学分析和光纤上实验室技术等领域找到应用。