低LUMO芘稠合氮杂蒽类化合物。
Low-LUMO pyrene-fused azaacenes.
作者信息
More Sandeep, Bhosale Rajesh, Mateo-Alonso Aurelio
机构信息
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018 Donostia-San Sebastian (Spain); School of Soft Matter Research, Freiburg Institute for Advanced Studies (FRIAS), Albert-Ludwigs-Universität Freiburg, Albertstraße 19, 79104 Freiburg (Germany); Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität Freiburg, Albertstraße 21, 79104 Freiburg (Germany).
出版信息
Chemistry. 2014 Aug 18;20(34):10626-31. doi: 10.1002/chem.201304461. Epub 2014 Feb 23.
A series of pyrene-fused azaacenes with four and six linearly fused rings that possess LUMO levels between -3.7 and -4.3 eV is reported. These LUMO values are remarkably lower than those typically observed for pyrene-fused azaacenes, even for systems with sixteen linearly fused rings, and are comparable to those observed for state-of-the-art n-azaacenes.
报道了一系列具有四个和六个线性稠合环的芘稠合氮杂并苯，其最低未占分子轨道（LUMO）能级在-3.7至-4.3电子伏特之间。这些LUMO值显著低于芘稠合氮杂并苯通常观察到的值，即使对于具有十六个线性稠合环的体系也是如此，并且与最先进的氮杂并苯所观察到的值相当。
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