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喹喔啉并菲并菲嗪（QPP）扩展的三苯并三喹吖啶（TBTQ）的合成与光电性质

Synthesis and Optoelectronic Properties of a Quinoxalino-Phenanthrophenazine (QPP) Extended Tribenzotriquinacene (TBTQ).

作者信息

Ueberricke Lucas, Punja Benke Bahiru, Kirschbaum Tobias, Hahn Sebastian, Rominger Frank, Bunz Uwe H F, Mastalerz Michael

机构信息

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.

出版信息

Chemistry. 2021 Jan 26;27(6):2043-2049. doi: 10.1002/chem.202003666. Epub 2020 Dec 22.

DOI:10.1002/chem.202003666
PMID:32954544
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7898691/
Abstract

A six-step synthesis towards a tribenzotriquinacene (TBTQ) bearing three quinoxalinophenanthrophenazine (QPP) units is presented. The optoelectronic properties are investigated and the effect of the three-dimensional arrangement of the individual QPP planes is examined using optical spectroscopy, electrochemical analysis and quantum-chemical calculations.

摘要

本文介绍了一种用于合成带有三个喹喔啉并菲咯嗪（QPP）单元的三苯并三喹吖嗪（TBTQ）的六步合成方法。研究了其光电性质，并使用光谱学、电化学分析和量子化学计算研究了各个QPP平面的三维排列的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/356e3c03a90c/CHEM-27-2043-g006.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/730fea515b0f/CHEM-27-2043-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/7a00800f57f2/CHEM-27-2043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/1f72fe6c17f0/CHEM-27-2043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/6e122a4a5b14/CHEM-27-2043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/596fc80eabd1/CHEM-27-2043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/356e3c03a90c/CHEM-27-2043-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/b74afd3fd6f4/CHEM-27-2043-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/626fc2d03e88/CHEM-27-2043-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/730fea515b0f/CHEM-27-2043-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/7a00800f57f2/CHEM-27-2043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/1f72fe6c17f0/CHEM-27-2043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/6e122a4a5b14/CHEM-27-2043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/596fc80eabd1/CHEM-27-2043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1ce/7898691/356e3c03a90c/CHEM-27-2043-g006.jpg

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3
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J Phys Chem B. 2019 Dec 19;123(50):10780-10793. doi: 10.1021/acs.jpcb.9b08031. Epub 2019 Dec 5.
5
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7
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