喹喔啉并菲并菲嗪（QPP）扩展的三苯并三喹吖啶（TBTQ）的合成与光电性质

Synthesis and Optoelectronic Properties of a Quinoxalino-Phenanthrophenazine (QPP) Extended Tribenzotriquinacene (TBTQ).

作者信息

Ueberricke Lucas, Punja Benke Bahiru, Kirschbaum Tobias, Hahn Sebastian, Rominger Frank, Bunz Uwe H F, Mastalerz Michael

机构信息

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.

出版信息

Chemistry. 2021 Jan 26;27(6):2043-2049. doi: 10.1002/chem.202003666. Epub 2020 Dec 22.

A six-step synthesis towards a tribenzotriquinacene (TBTQ) bearing three quinoxalinophenanthrophenazine (QPP) units is presented. The optoelectronic properties are investigated and the effect of the three-dimensional arrangement of the individual QPP planes is examined using optical spectroscopy, electrochemical analysis and quantum-chemical calculations.