用于多种铜（I）和金（I）氮杂环卡宾的“自动点击”功能化
'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs.
作者信息
Ibrahim Houssein, Gibard Clémentine, Hesling Cédric, Guillot Régis, Morel Laurent, Gautier Arnaud, Cisnetti Federico
机构信息
Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand, France.
出版信息
Dalton Trans. 2014 May 21;43(19):6981-9. doi: 10.1039/c4dt00429a. Epub 2014 Apr 3.
Azide-tagged Cu(I)-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting Cu(I) complexes are amenable to further transmetallation to Au(I). The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.
叠氮标记的Cu(I)-N-杂环卡宾在“自动点击”过程中发生反应，生成由带有不同取代基的1,2,3-三唑官能化的配合物。所得的Cu(I)配合物易于进一步转金属化为Au(I)。整个策略在温和的条件下进行，是一种高效合成带有生物相关基团的官能化金属-N-杂环卡宾的方法。
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