一种动态、形状可变聚合物颗粒的简便合成方法。
A facile synthesis of dynamic, shape-changing polymer particles.
作者信息
Klinger Daniel, Wang Cynthia X, Connal Luke A, Audus Debra J, Jang Se Gyu, Kraemer Stephan, Killops Kato L, Fredrickson Glenn H, Kramer Edward J, Hawker Craig J
机构信息
Materials Research Laboratory, University of California, Santa Barbara, CA 93106 (USA).
出版信息
Angew Chem Int Ed Engl. 2014 Jul 1;53(27):7018-22. doi: 10.1002/anie.201400183. Epub 2014 Apr 2.
Abstract
We herein report a new facile strategy to ellipsoidal block copolymer nanoparticles that exhibit a pH-triggered anistropic swelling profile. In a first step, elongated particles with an axially stacked lamellae structure are selectively prepared by utilizing functional surfactants to control the phase separation of symmetric polystyrene-b-poly(2-vinylpyridine) (PS-b-P2VP) in dispersed droplets. In a second step, the dynamic shape change is realized by cross-linking the P2VP domains, thereby connecting glassy PS discs with pH-sensitive hydrogel actuators.
摘要
我们在此报告一种制备椭圆形嵌段共聚物纳米粒子的新的简便策略，该纳米粒子呈现出pH触发的各向异性溶胀曲线。第一步，通过利用功能性表面活性剂控制对称聚苯乙烯-b-聚（2-乙烯基吡啶）（PS-b-P2VP）在分散液滴中的相分离，选择性地制备具有轴向堆叠层状结构的细长颗粒。第二步，通过交联P2VP域实现动态形状变化，从而将玻璃态PS圆盘与pH敏感水凝胶致动器连接起来。
相似文献
1
A facile synthesis of dynamic, shape-changing polymer particles.一种动态、形状可变聚合物颗粒的简便合成方法。
Angew Chem Int Ed Engl. 2014 Jul 1;53(27):7018-22. doi: 10.1002/anie.201400183. Epub 2014 Apr 2.
2
Stimuli-Responsive, Shape-Transforming Nanostructured Particles.刺激响应型，形状转变纳米结构粒子。
Adv Mater. 2017 Aug;29(29). doi: 10.1002/adma.201700608. Epub 2017 Jun 5.
3
Gold nanoparticles grown on star-shaped block copolymer monolayers.星形嵌段共聚物单层上生长的金纳米粒子。
Langmuir. 2011 Sep 6;27(17):10730-8. doi: 10.1021/la2022566. Epub 2011 Jul 26.
4
Shape and Color Switchable Block Copolymer Particles by Temperature and pH Dual Responses.温度和 pH 值双重响应形状和颜色可切换嵌段共聚物粒子。
ACS Nano. 2019 Apr 23;13(4):4230-4237. doi: 10.1021/acsnano.8b09276. Epub 2019 Mar 18.
5
Freezing polystyrene-b-poly(2-vinylpyridine) micelle nanoparticles with different nanostructures and sizes.冷冻具有不同纳米结构和尺寸的聚苯乙烯-b-聚（2-乙烯基吡啶）胶束纳米粒子。
Soft Matter. 2014 Apr 28;10(16):2848-55. doi: 10.1039/c3sm53049c.
6
Temperature-triggered micellization of block copolymers on an ionic liquid surface.温度引发嵌段共聚物在离子液体表面的胶束化。
Langmuir. 2011 Oct 18;27(20):12443-50. doi: 10.1021/la2024988. Epub 2011 Sep 19.
7
Determining the morphology of polystyrene-block-poly(2-vinylpyridine) micellar reactors for ZnO nanoparticle synthesis.测定用于 ZnO 纳米粒子合成的聚苯乙烯嵌段-聚(2-乙烯基吡啶)胶束反应器的形态。
Langmuir. 2010 May 18;26(10):7431-6. doi: 10.1021/la904143f.
8
Ordered complex nanostructures from bimodal self-assemblies of diblock copolymer micelles with solvent annealing.采用溶剂退火法从两亲性嵌段共聚物胶束的双峰自组装中有序合成复杂纳米结构。
Langmuir. 2011 Oct 4;27(19):12191-6. doi: 10.1021/la202664m. Epub 2011 Sep 12.
9
Differences of internal structures between amphiphilic and hydrophobic block-copolymer nanoparticles.两亲性和疏水性嵌段共聚物纳米颗粒内部结构的差异。
J Nanosci Nanotechnol. 2007 Mar;7(3):856-8. doi: 10.1166/jnn.2007.521.
10
Striped, ellipsoidal particles by controlled assembly of diblock copolymers.通过两嵌段共聚物的控制组装得到条纹状、椭圆形颗粒。
J Am Chem Soc. 2013 May 1;135(17):6649-57. doi: 10.1021/ja4019447. Epub 2013 Apr 17.
引用本文的文献
1
Bifunctional additive-driven shape transitions of block copolymer particles through synergistic quaternization and protonation.通过协同季铵化和质子化实现双功能添加剂驱动的嵌段共聚物颗粒形状转变
Chem Sci. 2025 Mar 8;16(15):6265-6272. doi: 10.1039/d5sc00259a. eCollection 2025 Apr 9.
2
Core-shell particle formation Co-assembly of AB diblock copolymers and nanoparticles in 3D soft confinement.核壳粒子形成：AB 二嵌段共聚物与纳米粒子在三维软受限环境中的共组装。
RSC Adv. 2024 Jul 15;14(31):22449-22458. doi: 10.1039/d4ra02223h. eCollection 2024 Jul 12.
3
Structure-Based Evaluation of Hybrid Lipid-Polymer Nanoparticles: The Role of the Polymeric Guest.基于结构的脂质-聚合物杂化纳米颗粒评估：聚合物客体的作用
Polymers (Basel). 2024 Jan 20;16(2):290. doi: 10.3390/polym16020290.
4
Morphological Evolution of Hybrid Block Copolymer Particles: Toward Magnetic Responsive Particles.杂化嵌段共聚物颗粒的形态演变：迈向磁响应颗粒
Polymers (Basel). 2023 Sep 7;15(18):3689. doi: 10.3390/polym15183689.
5
From shaping to functionalization of micro-droplets and particles.从微滴和颗粒的形成到功能化
Nanoscale Adv. 2021 May 26;3(12):3395-3416. doi: 10.1039/d1na00276g. eCollection 2021 Jun 15.
6
Regioselective Seeded Polymerization in Block Copolymer Nanoparticles: Post-Assembly Control of Colloidal Features.嵌段共聚物纳米颗粒中的区域选择性种子聚合：胶体特性的组装后控制
Angew Chem Int Ed Engl. 2022 Aug 26;61(35):e202208084. doi: 10.1002/anie.202208084. Epub 2022 Jul 21.
7
Dielectric and Mechanical Properties of CTAB-Modified Natural Rubber Latex-Cement Composites.十六烷基三甲基溴化铵改性天然橡胶乳胶-水泥复合材料的介电和力学性能
Polymers (Basel). 2022 Jan 13;14(2):320. doi: 10.3390/polym14020320.
8
Shape-Changing Particles: From Materials Design and Mechanisms to Implementation.变形粒子：从材料设计与机理到应用
Adv Mater. 2022 Jan;34(3):e2105758. doi: 10.1002/adma.202105758. Epub 2021 Nov 6.
9
Mesoscale Simulations of Polymer Solution Self-Assembly: Selection of Model Parameters within an Implicit Solvent Approximation.聚合物溶液自组装的中尺度模拟：隐式溶剂近似下模型参数的选择
Polymers (Basel). 2021 Mar 19;13(6):953. doi: 10.3390/polym13060953.
10
Responsive Nanostructured Polymer Particles.响应性纳米结构聚合物颗粒
Polymers (Basel). 2021 Jan 15;13(2):273. doi: 10.3390/polym13020273.
本文引用的文献
1
Supramolecular guests in solvent driven block copolymer assembly: From internally structured nanoparticles to micelles.溶剂驱动的嵌段共聚物组装中的超分子客体：从内部结构化纳米颗粒到胶束
Polym Chem. 2013 Oct 7;4(19):5038-5042. doi: 10.1039/C3PY00750B.
2
Thermally reversible aggregation of Gold nanoparticles in polymer nanocomposites through hydrogen bonding.聚合物纳米复合材料中通过氢键作用实现的金纳米颗粒的热可逆聚集。
Nano Lett. 2013 Nov 13;13(11):5297-302. doi: 10.1021/nl402813q. Epub 2013 Oct 28.
3
A dual functional layer for block copolymer self-assembly and the growth of nanopatterned polymer brushes.用于嵌段共聚物自组装和纳米图案化聚合物刷生长的双重功能层。
Langmuir. 2013 Oct 15;29(41):12858-65. doi: 10.1021/la403474k. Epub 2013 Oct 3.
4
Striped, ellipsoidal particles by controlled assembly of diblock copolymers.通过两嵌段共聚物的控制组装得到条纹状、椭圆形颗粒。
J Am Chem Soc. 2013 May 1;135(17):6649-57. doi: 10.1021/ja4019447. Epub 2013 Apr 17.
5
Shaping functional nano-objects by 3D confined supramolecular assembly.通过 3D 受限超分子组装来塑造功能纳米物体。
Small. 2013 Dec 20;9(24):4099-103. doi: 10.1002/smll.201300271. Epub 2013 Apr 4.
6
Swelling of block copolymer nanoparticles: a process combining deformation and phase separation.嵌段共聚物纳米粒子的肿胀：一种结合了形变和相分离的过程。
Langmuir. 2013 Apr 9;29(14):4640-6. doi: 10.1021/la400390b. Epub 2013 Mar 26.
7
Lattice deformation and domain distortion in the self-assembly of block copolymer thin films on chemical patterns.在化学图案上的嵌段共聚物薄膜自组装中晶格变形和畴畸变。
Small. 2013 Mar 11;9(5):779-84. doi: 10.1002/smll.201201950. Epub 2012 Nov 23.
8
Polarity-switching top coats enable orientation of sub-10-nm block copolymer domains.极性反转顶涂层可使亚 10nm 嵌段共聚物畴定向。
Science. 2012 Nov 9;338(6108):775-9. doi: 10.1126/science.1226046.
9
Mesoporous block copolymer nanoparticles with tailored structures by hydrogen-bonding-assisted self-assembly.通过氢键辅助自组装制备具有定制结构的介孔嵌段共聚物纳米粒子。
Adv Mater. 2012 Apr 10;24(14):1889-93. doi: 10.1002/adma.201200102. Epub 2012 Mar 7.
10
Suppression of the coffee-ring effect by shape-dependent capillary interactions.通过形状相关的毛细相互作用抑制咖啡环效应。
Nature. 2011 Aug 17;476(7360):308-11. doi: 10.1038/nature10344.
Zotero 插件