State Key Laboratory of Materials-Orient Chemical Engineering, College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, People's Republic of China.
Nanoscale. 2014 May 21;6(10):5516-25. doi: 10.1039/c4nr00644e.
A new type of inner-motile photocatalyst film is explored to enhance photocatalytic performance using magnetically actuated artificial cilia. The inner-motile photocatalyst film is capable of generating flow and mixing on the microscale because it produces a motion similar to that of natural cilia when it is subjected to a rotational magnetic field. Compared with traditional photocatalyst films, the inner-motile photocatalyst film exhibits the unique ability of microfluidic manipulation. It uses an impactful and self-contained design to accelerate interior mass transfer and desorption of degradation species. Moreover, the special cilia-like structures increase the surface area and light absorption. Consequently, the photocatalytic activity of the inner-motile photocatalyst film is dramatically improved to approximately 3.0 times that of the traditional planar film. The inner-motile photocatalyst film also exhibits high photocatalytic durability and can be reused several times with ease. Furthermore, this feasible yet versatile platform can be extended to other photocatalyst systems, such as TiO2, P25, ZnO, and Co3O4 systems, to improve their photocatalytic performance.
探索了一种新型内驱动机光催化剂膜,利用磁驱动人工纤毛来提高光催化性能。内驱动机光催化剂膜能够在微尺度上产生流动和混合,因为当它受到旋转磁场时,会产生类似于天然纤毛的运动。与传统的光催化剂膜相比,内驱动机光催化剂膜具有独特的微流操控能力。它采用有冲击力的自包含设计来加速内部传质和降解物种的解吸。此外,特殊的纤毛状结构增加了表面积和光吸收。因此,内驱动机光催化剂膜的光催化活性显著提高,约为传统平面膜的 3.0 倍。内驱动机光催化剂膜还表现出高的光催化耐久性,并且可以轻松重复使用几次。此外,这个可行而通用的平台可以扩展到其他光催化剂系统,如 TiO2、P25、ZnO 和 Co3O4 系统,以提高它们的光催化性能。