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Y2O3:Eu纳米棒的一维结构:可控合成、生长机制及发光特性

1D structure of Y2O3:Eu nanorods: controllable synthesis, growth mechanisms and luminescence properties.

作者信息

Wang Qin, Guo Jing, Jia Wenjing, Liul Baocang, Liu Yongxin, Xu Guangran, Liu Yang, Hu Wenting, Zhang Jun

出版信息

J Nanosci Nanotechnol. 2014 May;14(5):3433-9. doi: 10.1166/jnn.2014.7989.

Abstract

Y2O3O:Eu nanorods were successfully synthesized by a facile and effective hydrothermal method in the presence of P123 (EO106PO70EO106) as the surfactant followed by a subsequent heat treatment process. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images indicate that the as-prepared samples consist of nanorods with diameters ranging from 80 nm to 100 nm and grow along the (100) direction. The growth mechanism of the as-obtained Y2O3:Eu nanorods was proposed on the basis of pH-dependent experiments. It is found that the pH is a crucial factor in determining the phase, morphology and luminescence properties of Y2O3:Eu nanorods. The luminescent spectra of Y2O3:Eu nanorods show the strong characteristic dominant emission of the Eu3+ ions at 613 nm.

摘要

在表面活性剂P123(EO106PO70EO106)存在的情况下,通过简便有效的水热法成功合成了Y2O3:Eu纳米棒,随后进行了热处理过程。扫描电子显微镜(SEM)和透射电子显微镜(TEM)图像表明,所制备的样品由直径范围为80纳米至100纳米的纳米棒组成,并沿(100)方向生长。基于pH依赖性实验提出了所获得的Y2O3:Eu纳米棒的生长机制。发现pH是决定Y2O3:Eu纳米棒的相、形态和发光性质的关键因素。Y2O3:Eu纳米棒的发光光谱显示Eu3+离子在613纳米处有强烈的特征性主导发射。

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