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Yb(3+)-Er(3+)共掺杂氟磷酸盐玻璃的结构起源与发光性能分析。

Analysis of structure origin and luminescence properties of Yb(3+)-Er(3+) co-doped fluorophosphate glass.

机构信息

College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, PR China.

Institute of Optoelectronic Technology, China Jiliang University, Hangzhou 310018, PR China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2014 Aug 14;129:235-40. doi: 10.1016/j.saa.2014.03.035. Epub 2014 Mar 28.

Abstract

The near infrared luminescence properties of Yb(3+)-Er(3+) co-doped fluorophosphate glasses have been investigated. The various effects on structure and 1.53 μm emission were analyzed as a function of Yb(3+) concentration. The energy transfer mechanism was proposed. High measured lifetime (10.75 ms), large effective full widths at half maximum (73.71 nm) and large gain per unit length (62.8 × 10(-)(24)cm(2)s) have been achieved in prepared glass. The present glass co-doped with 6mol% YbF3 and 2 mol% ErF3 showed magnificent luminescence properties for telecommunication application.

摘要

研究了共掺 Yb(3+)-Er(3+)氟磷酸盐玻璃的近红外发光性能。分析了不同 Yb(3+)浓度对结构和 1.53μm 发射的各种影响。提出了能量传递机制。在制备的玻璃中获得了高的测量寿命(10.75ms)、大的有效全宽(73.71nm)和单位长度的大增益(62.8×10(-)(24)cm(2)s)。本研究共掺杂 6mol%YbF3 和 2mol%ErF3 的玻璃在电信应用中表现出优异的发光性能。

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