Muruganandham M, Suri Rominder P S, Sillanpää Mika, Wu Jerry J, Ahmmad Bashir, Balachandran S, Swaminathan M
J Nanosci Nanotechnol. 2014 Feb;14(2):1898-910. doi: 10.1166/jnn.2014.8718.
This article reports on recent developments in heterogeneous AOP processes such as photocatalysis, Fenton-like process and catalytic ozonation. The principle, mechanism, and influence of experimental conditions on the degradation of pollutants in heterogeneous catalytic ozonation and the photocatalytic process were discussed. Introducing solid catalysts substantially increased the efficiency of the ozonation process by producing hydroxyl radicals in the degradation process. The different types of catalyst, catalyst dosage, solution pH, ozone flow rate, water matrix and catalytic reusability and stability are reported on here. The list of various semiconductor materials used as photocatalysts, their light absorption properties, various light sources and surface properties such as surface area, pore size and pore volume as a factor in the photocatalytic degradation of various pollutants are discussed. The review article also discussed the pollutants degraded using these three processes.
本文报道了多相AOP过程的最新进展,如光催化、类芬顿过程和催化臭氧化。讨论了多相催化臭氧化和光催化过程中实验条件对污染物降解的原理、机制和影响。引入固体催化剂通过在降解过程中产生羟基自由基,大大提高了臭氧化过程的效率。本文报道了不同类型的催化剂、催化剂用量、溶液pH值、臭氧流速、水基质以及催化的可重复使用性和稳定性。讨论了用作光催化剂的各种半导体材料的清单、它们的光吸收特性、各种光源以及诸如表面积、孔径和孔体积等表面特性作为各种污染物光催化降解的一个因素。这篇综述文章还讨论了使用这三种过程降解的污染物。