Essoumhi Abdellatif, El Kazzouli Saïd, Bousmina Mosto
J Nanosci Nanotechnol. 2014 Feb;14(2):2012-23. doi: 10.1166/jnn.2014.9013.
This review reports on the recent advances in the synthesis and physico-chemical properties of palladium-containing perovskites. Initially, the perovskite structure is briefly reviewed, then palladium-containing perovskites synthesis and physico-chemical properties are detailed. The applications of palladium-containing perovskites in catalysis; namely, NO reduction, methane combustion, methanol as well as ethanol oxidation, are briefly highlighted. The involvement and the important contribution of palladium-containing perovskites in cross-coupling reactions, especially Suzuki-Miyaura, Sonogashira, Ulmann and Grignard, are discussed.
本综述报道了含钯钙钛矿在合成及物理化学性质方面的最新进展。首先，简要回顾了钙钛矿结构，然后详细阐述了含钯钙钛矿的合成及物理化学性质。简要强调了含钯钙钛矿在催化领域的应用，即NO还原、甲烷燃烧、甲醇以及乙醇氧化。讨论了含钯钙钛矿在交叉偶联反应中的参与情况及其重要贡献，特别是铃木-宫浦反应、园田-薗头反应、乌尔曼反应和格氏反应。
