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通过少层氧化石墨烯的分散改善油润滑剂的摩擦学行为

Oil lubricant tribological behaviour improvement through dispersion of few layer graphene oxide.

作者信息

Sarno Maria, Senatore Adolfo, Cirillo Claudia, Petrone Vincenzo, Ciambelli Paolo

出版信息

J Nanosci Nanotechnol. 2014 Jul;14(7):4960-8. doi: 10.1166/jnn.2014.8673.

Abstract

Few layer graphene oxide (GO) nanosheets were prepared by a very fast modified Hummers method and widely characterized. Avoiding further chemical reactions, trying to take advantage of the easy exfoliation of GO favoring the formation of a tribofilm, and using a methodology well known to the lubricant industry, they were added to a mineral oil by the help of a dispersant. The tribological behaviour of GO in mineral oil was investigated under a wide spectrum of conditions, from boundary and mixed lubrication to elastohydrodynamic regimes. A ball on disc setup tribometer has been used to verify the friction reduction due to nanosheets dispersed in mineral oil. Their good friction and anti-wear properties may possibly be attributed to the small and extremely thin laminated structure, which offer lower shear stress and prevent interaction between metal interfaces. Furthermore, the results clearly prove that graphene platelets in oil easily form a protective film to prevent the direct contact between steel surfaces and, thereby, improving the frictional behaviour of the base oil. This evidence is also related to the frictional coefficient trend in boundary regime.

摘要

通过一种非常快速的改进型Hummers方法制备了几层氧化石墨烯(GO)纳米片,并对其进行了广泛表征。为避免进一步的化学反应,尝试利用氧化石墨烯易于剥离的特性以利于形成摩擦膜,并采用润滑剂行业熟知的方法,借助分散剂将它们添加到矿物油中。在从边界润滑和混合润滑到弹性流体动力润滑等广泛的条件下,研究了氧化石墨烯在矿物油中的摩擦学行为。使用球盘式摩擦磨损试验机来验证由于纳米片分散在矿物油中而导致的摩擦降低。它们良好的摩擦和抗磨性能可能归因于其小且极薄的层状结构,该结构提供较低的剪切应力并防止金属界面之间的相互作用。此外,结果清楚地证明,油中的石墨烯片易于形成保护膜,以防止钢表面直接接触,从而改善基础油的摩擦行为。这一证据也与边界润滑状态下的摩擦系数趋势有关。

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