Tsujimoto Y, Sathish C I, Matsushita Y, Yamaura K, Uchikoshi T
Materials Processing Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan.
Chem Commun (Camb). 2014 Jun 4;50(44):5915-8. doi: 10.1039/c4cc01422g.
New members of Ruddlesden-Popper type layered oxychloride compounds, Sr2MO2Cl2 (M = Mn, Ni) and Ba2PdO2Cl2, were synthesized under high-pressure conditions. Synchrotron XRD analysis revealed that all the phases adopt the tetragonal space group I4/mmm, where two-dimensional sheets composed of corner-sharing MO4/PdO4 squares were separated by rock-salt SrCl/BaCl layers.
在高压条件下合成了Ruddlesden-Popper型层状氯氧化物化合物的新成员，即Sr2MO2Cl2（M = Mn，Ni）和Ba2PdO2Cl2。同步辐射XRD分析表明，所有相均采用四方空间群I4/mmm，其中由角共享MO4/PdO4正方形组成的二维片层被岩盐SrCl/BaCl层隔开。
