双（硫氰酸根合-κN）[三（吡啶-2-基甲基）胺-κ(4)N]铁（II）
Bis-(thio-cyanato-κN)[tris(pyridin-2-yl-meth-yl)amine-κ(4) N]-iron(II).
作者信息
Dai Jing-Wei, Li Zhao-Yang, Sato Osamu
机构信息
Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan.
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 8;70(Pt 2):m35. doi: 10.1107/S1600536813034818. eCollection 2014 Feb 1.
In the title complex, [Fe(NCS)2(C18H18N4)], the Fe(II) cation is chelated by a tris-(2-pyridyl-meth-yl)amine ligand and coordin-ated by two thio-cyanate anions in a distorted N6 octa-hedral geometry. In the crystal, weak C-H⋯S hydrogen bonds and π-π stacking inter-actions between parallel pyridine rings of adjacent mol-ecules [centroid-centroid distance = 3.653 (3) Å] link the mol-ecules into a two-dimensional supra-molecular architecture. The structure contains voids of 124 (9) Å(3), which are free of solvent molecules.
在标题配合物[Fe(NCS)₂(C₁₈H₁₈N₄)]中，Fe(II)阳离子由三(2 - 吡啶甲基)胺配体螯合，并由两个硫氰酸根阴离子配位，形成扭曲的N₆八面体几何构型。在晶体中，相邻分子平行吡啶环之间的弱C—H⋯S氢键和π - π堆积相互作用[质心 - 质心距离 = 3.653(3) Å]将分子连接成二维超分子结构。该结构包含124(9) ų的空隙，其中没有溶剂分子。
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