Rivera Augusto, Jiménez-Cruz Leonardo, Bolte Michael
Universidad Nacional de Colombia, Sede Bogotá, Facultad de Ciencias, Departamento de Química, Cra 30 No.45-03, Bogotá, Código Postal 111321, Colombia.
Institut für Anorganische Chemie, J.-W.-Goethe-Universität, Max-von-Laue-Strasse 7, Frankfurt/Main, D-60438, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 22;70(Pt 2):o177. doi: 10.1107/S1600536814000841. eCollection 2014 Feb 1.
In the title solvate, C14H12N2O·0.5C6H6, the complete benzene molecule is generated by a crystallographic inversion centre. The dihedral angle between the planes of the benzimidazole moiety and the phenol substituent is 75.28 (3)°. In the crystal, O-H⋯N hydrogen bonds link the mol-ecules into parallel chains propagating along [100]. The mol-ecules are further connected by C-H⋯π inter-actions.
在标题溶剂化物C₁₄H₁₂N₂O·0.5C₆H₆中，完整的苯分子由一个晶体学反演中心产生。苯并咪唑部分平面与酚取代基平面之间的二面角为75.28 (3)°。在晶体中，O—H⋯N氢键将分子连接成沿[100]方向传播的平行链。分子通过C—H⋯π相互作用进一步连接。
