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3-氨基-5,5-二苯基-咪唑烷-2,4-二酮

3-Amino-5,5-di-phenyl-imidazolidine-2,4-dione.

作者信息

Mague Joel T, Abdel-Aziz Alaa A-M, El-Azab Adel S

机构信息

Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.

Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh 11451, Saudi Arabia ; Department of Medicinal Chemistry, Faculty of Pharmacy, University of Mansoura, Mansoura 35516, Egypt.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 8;70(Pt 3):o262-3. doi: 10.1107/S1600536814002487. eCollection 2014 Mar 1.

DOI:10.1107/S1600536814002487
PMID:24764978
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998397/
Abstract

The title compound, C15H13N3O2, crystallizes with two independent mol-ecules in the asymmetric unit, which differ considerably in the dihedral angles made between the phenyl groups and the five-membered rings [47.19 (8) and 61.16 (9)° in one mol-ecule and 55.04 (10) and 55.00 (8)° in the other]. In the crystal, N-H⋯O hydrogen bonds generate columnar units having approximate fourfold rotational symmetry about axes parallel to b.

摘要

标题化合物C15H13N3O2在不对称单元中以两个独立分子结晶，这两个分子中苯基与五元环之间形成的二面角差异很大[一个分子中为47.19 (8)和61.16 (9)°，另一个分子中为55.04 (10)和55.00 (8)°]。在晶体中，N—H⋯O氢键形成了沿平行于b轴具有近似四重旋转对称性的柱状单元。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c43/3998397/62c5082c82df/e-70-0o262-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c43/3998397/3708a562eda7/e-70-0o262-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c43/3998397/62c5082c82df/e-70-0o262-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c43/3998397/3708a562eda7/e-70-0o262-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c43/3998397/62c5082c82df/e-70-0o262-fig2.jpg

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