N(1),N(4)-二苯基-3,6-双-(苯基-亚氨基)-环己-1,4-二烯-1,4-二胺
N (1),N (4)-Diphenyl-3,6-bis-(phenyl-imino)-cyclo-hexa-1,4-diene-1,4-di-amine.
作者信息
Ohno Keiji, Maruyama Haruki, Fujihara Takashi, Nagasawa Akira
机构信息
Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-Okubo 255, Sakura-ku, Saitama 338-8570, Japan.
Comprehensive Analysis Center for Science, Saitama University, Shimo-Okubo 255, Sakura-ku, Saitama 338-8570, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):o303-4. doi: 10.1107/S1600536814002906. eCollection 2014 Mar 1.
In the title compound, C30H24N4, the central benzo-quinonedi-imine moiety is approximately planar, with a maximum deviation of 0.044 (14) Å. The four terminal phenyl rings are twisted by 44.95 (11), 54.90 (10), 44.98 (10) and 50.68 (11)° with respect to the mean plane the benzo-quinonedi-imine unit. In the crystal, mol-ecules are linked by weak C-H⋯π inter-actions into supra-molecular chains running along the b-axis direction.
在标题化合物C₃₀H₂₄N₄中，中心苯并醌二亚胺部分近似平面，最大偏差为0.044 (14) Å。四个末端苯环相对于苯并醌二亚胺单元的平均平面扭转了44.95 (11)、54.90 (10)、44.98 (10)和50.68 (11)°。在晶体中，分子通过弱C-H⋯π相互作用连接成沿b轴方向延伸的超分子链。
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