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2 - ((E)-{4 - [双(4 - 乙氧基 - 苯基)氨基] - 苯基}亚氨基 - 甲基)苯酚

2-((E)-{4-[Bis(4-eth-oxy-phen-yl)amino]-phen-yl}imino-meth-yl)phenol.

作者信息

Gao Bing-Fei, Jin Zhe-Peng, Chen Jiang, Tian Yu-Peng

机构信息

Department of Chemistry, Anhui University, Hefei 230039, People's Republic of China ; Key Laboratory of Functional Inorganic Materials Chemistry, Hefei 230039, People's Republic of China.

Department of Chemistry, Bengbu Medical College, Bengbu 233030, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):o313. doi: 10.1107/S1600536814003201. eCollection 2014 Mar 1.

DOI:10.1107/S1600536814003201
PMID:24765014
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998452/
Abstract

In the title Schiff base mol-ecule, C29H28N2O3, the three terminal benzene rings are twisted by 73.84 (15), 81.25 (16) and 12.1 (2)° with respect to the central benzene ring. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal, mol-ecules are linked via weak C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.

摘要

在席夫碱分子C29H28N2O3中,三个末端苯环相对于中心苯环扭转的角度分别为73.84 (15)°、81.25 (16)°和12.1 (2)°。分子内存在O—H⋯N氢键。在晶体中,分子通过弱C—H⋯π相互作用连接成三维超分子结构。

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本文引用的文献

1
4-Chloro-2-[(E)-(4-fluoro-phen-yl)imino-meth-yl]phenol.4-氯-2-[(E)-(4-氟苯基)亚氨基甲基]苯酚
Acta Crystallogr Sect E Struct Rep Online. 2013 Dec 14;70(Pt 1):o42. doi: 10.1107/S1600536813033278. eCollection 2014 Jan 1.
2
2-{(E)-[(2-Methyl-3-nitro-phen-yl)imino]-meth-yl}-4-nitro-phenol.2-{(E)-[(2-甲基-3-硝基苯基)亚氨基]-甲基}-4-硝基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 12;69(Pt 7):o1085. doi: 10.1107/S1600536813015407. eCollection 2013.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.