2-((1E)-1-{2-[(2Z)-4-(4-溴苯基)-3-苯基-2,3-二氢-1,3-噻唑-2-亚基]肼-1-亚基}乙基)吡啶-1-ium溴化物一水合物
2-((1E)-1-{2-[(2Z)-4-(4-Bromo-phen-yl)-3-phenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.
作者信息
Mague Joel T, Mohamed Shaaban K, Akkurt Mehmet, Abd El-Alaziz Ahmed T, Albayati Mustafa R
机构信息
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 22;70(Pt 3):o328-9. doi: 10.1107/S160053681400347X. eCollection 2014 Mar 1.
In the title hydrated molecular salt, C22H18BrN4S(+)·Br(-)·H2O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thia-zole ring. In the crystal, mol-ecules are linked into chains running parallel to the a axis by association of the bromide ions and the water mol-ecules of crystallization with the cations via N-H⋯O, O-H⋯Br, C-H⋯N and C-H⋯Br hydrogen-bonding inter-actions. C-H⋯π and C-Br⋯π [3.7426 (11) Å, 161.73 (7)°] inter-actions are also observed, forming infinite chains extending along the b-axis direction.
在标题水合分子盐C22H18BrN4S(+)·Br(-)·H2O中，芳环与噻唑环的二面角为14.20 (12)°、34.29 (10)°和68.75 (11)°。在晶体中，分子通过溴离子和结晶水分子与阳离子之间的N-H⋯O、O-H⋯Br、C-H⋯N和C-H⋯Br氢键相互作用连接成平行于a轴的链。还观察到C-H⋯π和C-Br⋯π [3.7426 (11) Å，161.73 (7)°]相互作用，形成沿b轴方向延伸的无限链。
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