4-((1E)-1-{(2Z)-2-[4-(4-溴苯基)-3-苯基-2,3-二氢-1,3-噻唑-2-亚基]肼-1-亚基}乙基)苯酚半水合物的晶体结构
Crystal structure of 4-((1E)-1-{(2Z)-2-[4-(4-bromo-phen-yl)-3-phenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)phenol hemihydrate.
作者信息
Mague Joel T, Akkurt Mehmet, Mohamed Shaaban K, Hassan Alaa A, Albayati Mustafa R
机构信息
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 24;70(Pt 10):o1124-5. doi: 10.1107/S1600536814019473. eCollection 2014 Oct 1.
In the title compound, C23H18BrN3OS·0.5H2O, the bromo-phenyl, phenyl and phenol rings make dihedral angles of 46.5 (1), 66.78 (8) and 15.4 (2)°, respectively, with the mean squares plane of the thia-zol-idene ring. In the crystal, the lattice water mol-ecule is hydrogen bonded to the phenol group and makes a weaker O-H⋯N connection to an inversion-related mol-ecule, forming a ring while weak pairwise C-H⋯S inter-actions involving inversion-related mol-ecules form a second ring. Both these motifs result in the formation of two-dimensional networks lying parallel to (10-1).
在标题化合物C23H18BrN3OS·0.5H2O中，溴苯基、苯基和苯酚环与噻唑啉环的均方平面分别形成46.5 (1)°、66.78 (8)°和15.4 (2)°的二面角。在晶体中，晶格水分子通过氢键与酚基团相连，并与一个与其呈反演关系的分子形成较弱的O-H⋯N连接，形成一个环，而涉及反演相关分子的弱成对C-H⋯S相互作用形成第二个环。这两种结构基元导致形成平行于(10-1)的二维网络。
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