• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-硝基-联苯-4,4'-二甲酸二甲酯

Dimethyl 2-nitro-biphenyl-4,4'-di-carboxyl-ate.

作者信息

Vieira Vanessa C M, Golen James A, Rheingold Arnold L, Manke David R

机构信息

Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA.

Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 28;70(Pt 3):o371. doi: 10.1107/S1600536814004218. eCollection 2014 Mar 1.

DOI:10.1107/S1600536814004218
PMID:24765053
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998483/
Abstract

The title compound, C16H13NO6, exhibits a biphenyl unit with a dihedral angle between the two aryl rings of 56.01 (5)°. The two ester groups vary slightly from planarity, with ar-yl-ester dihedral angles of 4.57 (5) and 16.73 (5)°. The nitro group is turned from the aromatic unit with an ar-yl-nitro dihedral angle of 48.66 (4)°. In the crystal, mol-ecules are connected by weak C-H⋯O inter-actions, forming a three-dimensional network.

摘要

标题化合物C₁₆H₁₃NO₆呈现出一个联苯单元，两个芳环之间的二面角为56.01 (5)°。两个酯基与平面略有偏差，芳基 - 酯二面角分别为4.57 (5)°和16.73 (5)°。硝基相对于芳环单元发生扭转，芳基 - 硝基二面角为48.66 (4)°。在晶体中，分子通过弱C - H⋯O相互作用连接，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3c1/3998483/7137342cca03/e-70-0o371-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3c1/3998483/b836c0c27aed/e-70-0o371-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3c1/3998483/7137342cca03/e-70-0o371-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3c1/3998483/b836c0c27aed/e-70-0o371-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3c1/3998483/7137342cca03/e-70-0o371-fig2.jpg

相似文献

1
Dimethyl 2-nitro-biphenyl-4,4'-di-carboxyl-ate.2-硝基-联苯-4,4'-二甲酸二甲酯
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 28;70(Pt 3):o371. doi: 10.1107/S1600536814004218. eCollection 2014 Mar 1.
2
Dimethyl 2,2'-di-nitro-biphenyl-4,4'-di-carboxyl-ate.2,2'-二硝基联苯-4,4'-二羧酸二甲酯
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):o305. doi: 10.1107/S1600536814003067. eCollection 2014 Mar 1.
3
Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di-hydro-pyridine-3,5-di-carboxyl-ate.4-（联苯-4-基）-2,6-二甲基-1,4-二氢吡啶-3,5-二羧酸二乙酯
Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 18;70(Pt 7):o791-2. doi: 10.1107/S1600536814013294. eCollection 2014 Jul 1.
4
Dimethyl 2-amino-biphenyl-4,4'-di-carboxyl-ate.2-氨基-联苯-4,4'-二甲酸二甲酯
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 27;69(Pt 5):o797. doi: 10.1107/S1600536813010775. Print 2013 May 1.
5
The co-crystal N,N'-bis-[(pyridin-1-ium-2-yl)meth-yl]ethane-dithio-amide bis-(2,6-di-nitro-benzoate)-2,6-di-nitro-benzoic acid (1/4).共晶体N，N'-双-[(吡啶-1-鎓-2-基)甲基]乙二硫酰胺双-(2,6-二硝基苯甲酸酯)-2,6-二硝基苯甲酸(1/4)
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 4;69(Pt 10):o1506-7. doi: 10.1107/S1600536813023490. eCollection 2013.
6
Crystal structures of three N-(aryl-sulfon-yl)-4-fluoro-benzamides.三种N-（芳基磺酰基）-4-氟苯甲酰胺的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 31;72(Pt 4):575-82. doi: 10.1107/S2056989016005089. eCollection 2016 Apr 1.
7
Methyl 3-[4-(4-nitro-benz-yloxy)phen-yl]propano-ate.3-[4-(4-硝基苄氧基)苯基]丙酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o1997-8. doi: 10.1107/S1600536812024701. Epub 2012 Jun 2.
8
(3aR*,8bR*)-3a,8b-Dihy-droxy-1-(4-methyl-phen-yl)-2-methyl-sulfanyl-3-nitro-1,8b-di-hydro-indeno-[1,2-b]pyrrol-4(3aH)-one.
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 12;70(Pt 3):o279-80. doi: 10.1107/S1600536814002712. eCollection 2014 Mar 1.
9
Crystal structures of three 1-oxo-1,2-di-hydro-naphthalene derivatives: dimethyl 4-(4-meth-oxy-phen-yl)-2-(4-methyl-phen-yl)-1-oxo-1,2-di-hydro-naphthalene-2,3-di-carboxyl-ate, dimethyl 1-oxo-2-(pyren-4-yl)-4-(thio-phen-2-yl)-1,2-di-hydro-naphthalene-2,3-di-carboxyl-ate and ethyl 1-oxo-2-phenyl-2,4-bis-(thio-phen-2-yl)-1,2-di-hydro-naphthalene-3-carboxyl-ate.三种1-氧代-1,2-二氢萘衍生物的晶体结构：4-(4-甲氧基苯基)-2-(4-甲基苯基)-1-氧代-1,2-二氢萘-2,3-二羧酸二甲酯、1-氧代-2-(芘-4-基)-4-(噻吩-2-基)-1,2-二氢萘-2,3-二羧酸二甲酯和1-氧代-2-苯基-2,4-双(噻吩-2-基)-1,2-二氢萘-3-羧酸乙酯。
Acta Crystallogr E Crystallogr Commun. 2017 Jan 13;73(Pt 2):177-182. doi: 10.1107/S2056989017000469. eCollection 2017 Feb 1.
10
Methyl 3-[(1,1-dioxo-1λ(6),2-benzothiazol-3-yl)amino]-5-nitrothiophene-2-carboxyl-ate.
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2951-2. doi: 10.1107/S1600536812038378. Epub 2012 Sep 19.

本文引用的文献

1
Synthesis, structure, topology and magnetic properties of cobalt(II) coordination polymers with 2-nitrobiphenyl-4,4'-dicarboxylic acid and bis(pyridyl) ligands.2-硝基联苯-4,4'-二甲酸和双（吡啶基）配体的钴（II）配位聚合物的合成、结构、拓扑和磁性。
Dalton Trans. 2012 Dec 21;41(47):14316-28. doi: 10.1039/c2dt31917a.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.