Kim Bo Seong, Lee Jun Yeob
Department of Polymer Science and Engineering, Dankook University Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do 448-701, Korea.
ACS Appl Mater Interfaces. 2014 Jun 11;6(11):8396-400. doi: 10.1021/am501301g. Epub 2014 Apr 28.
Highly efficient thermally activated delayed fluorescence devices were developed using a bipolar host material, 2,7-bis(diphenylphosphoryl)-9-phenyl-9H-carbazole (PPO27), derived from carbazole and diphenylphosphine oxide. The PPO27 host was effective for good charge balance and energy transfer from the PPO27 host to thermally activated delayed fluorescence dopant. The PPO27 device doped with (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile dopant could realize a high quantum efficiency of 24.2%.