Kawamura Akifumi, Kiguchi Tadahiro, Nishihata Takeshi, Uragami Tadashi, Miyata Takashi
Department of Chemistry and Materials Engineering, Kansai University, 3-3-35, Yamate-cho, Suita, Osaka 564-8680, Japan.
Chem Commun (Camb). 2014 Oct 4;50(76):11101-3. doi: 10.1039/c4cc01187b.
Target molecule-responsive hydrogels with β-cyclodextrin (β-CD) were prepared via molecular imprinting using bisphenol A (BPA) as a template. BPA-imprinted hydrogels showed greater shrinkage than non-imprinted hydrogels because CD ligands arranged at suitable positions formed CD-BPA-CD complexes that acted as crosslinks.
以双酚A（BPA）为模板，通过分子印迹法制备了含β-环糊精（β-CD）的目标分子响应水凝胶。BPA印迹水凝胶比非印迹水凝胶表现出更大的收缩，这是因为排列在合适位置的CD配体形成了作为交联剂的CD-BPA-CD复合物。
