具有高低压下高储气能力的共聚多孔有机骨架的合成。
Synthesis of copolymerized porous organic frameworks with high gas storage capabilities at both high and low pressures.
作者信息
Pei Cuiying, Ben Teng, Li Yanqiang, Qiu Shilun
机构信息
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, China.
出版信息
Chem Commun (Camb). 2014 Jun 11;50(46):6134-6. doi: 10.1039/c4cc00302k.
PMID:24776945
Abstract
A series of copolymerized porous organic frameworks (C-POFs) were synthesized with monomers of tetrakis(4-bromophenyl)methane and tris(4-bromophenyl)amine in different ratios by a Yamamoto-type Ullmann cross-coupling reaction. These C-POFs exhibit high physicochemical stability, large surface areas and excellent H2, CH4 and CO2 adsorption properties both at low and high pressures.
摘要
通过山本型乌尔曼交叉偶联反应，以不同比例的四（4-溴苯基）甲烷和三（4-溴苯基）胺为单体合成了一系列共聚多孔有机骨架材料（C-POFs）。这些C-POFs在低压和高压下均表现出高物理化学稳定性、大表面积以及优异的H2、CH4和CO2吸附性能。
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