Wang Xing, Yang Yanyu, Gao Peiyuan, Li Dan, Yang Fei, Shen Hong, Guo Hongxia, Xu Fujian, Wu Decheng
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics & Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Chem Commun (Camb). 2014 Jun 11;50(46):6126-9. doi: 10.1039/c4cc01859a.
Here, we demonstrate the first known approach to create G1 and G2 POSS dendrimers with 9 and 65 POSS units, and 56 and 392 terminal vinyl groups from a 1 → 7 branching monomer in only one and three steps.
在此,我们展示了第一种已知的方法,可从一种1→7支化单体出发,仅通过一步和三步分别制备出具有9个和65个POSS单元、56个和392个末端乙烯基的G1和G2 POSS树枝状大分子。