含多个孔的金属卟啉骨架用于高效和选择性环氧化反应。
Metalloporphyrinic framework containing multiple pores for highly efficient and selective epoxidation.
作者信息
Yang Xiu-Li, Wu Chuan-De
机构信息
Center for Chemistry of High-Performance and Novel Materials, Department of Chemistry, Zhejiang University , Hangzhou 310027, P. R. China.
出版信息
Inorg Chem. 2014 May 19;53(10):4797-9. doi: 10.1021/ic500531k. Epub 2014 May 2.
PMID:24787447
Abstract
Metalloporphyrin Mn(III)Cl-5,10,15,20-tetrakis(3,5-biscarboxylphenyl)porphyrin, having eight carboxylate groups in multiple coordination modes, connects with paddle-wheel Zn2(COO)4 units for the construction of an interesting porous porphyrinic framework that demonstrates high efficiency and stability upon epoxidation of olefins with excellent substrate size selectivity.
摘要
金属卟啉Mn(III)Cl-5,10,15,20-四(3,5-二羧基苯基)卟啉具有八个处于多种配位模式的羧酸盐基团，与桨轮状Zn2(COO)4单元相连，用于构建一个有趣的多孔卟啉框架，该框架在烯烃环氧化反应中表现出高效率和稳定性，对底物尺寸具有出色的选择性。
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