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Mild solvothermal syntheses and characterization of layered copper thioantimonates(III) and thioarsenate(III).

作者信息

Zhang Chi, Ji Min, Ji Shou-Hua, An Yong-Lin

机构信息

School of Chemistry and ‡Testing Center of Material, Dalian University of Technology , Dalian 116024, People's Republic of China.

出版信息

Inorg Chem. 2014 May 19;53(10):4856-60. doi: 10.1021/ic402864s. Epub 2014 May 7.

DOI:10.1021/ic402864s
PMID:24806841
Abstract

The new copper thioantimonates(III) and thioarsenate(III) Rb2Cu2Sb2S5 (1), Cs2Cu2Sb2S5 (2), and Rb8Cu6As8S19 (3) have been synthesized solvothermally. Compound 1 contains a [Cu2SbS3] net to which [Sb2S4] chains adhere through Cu-S bonds and Sb-Cu interactions to give a layered structure. In compound 2, the layer is formed by edge-sharing tetrahedral CuS4 chains linked by dimeric [Sb2S5] units. The layered structure in compound 3 is constructed by helical chains built from [Cu3S7] moieties and dimeric [As2S5] units which are further connected by tetrameric [As4S9] groups. Their optical and thermal properties have been investigated.

摘要

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