单齿配体在基于五齿配体的钴配合物光催化产氢中的意外作用。
An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes.
作者信息
Xie Jingfan, Zhou Qianxiong, Li Chao, Wang Weibo, Hou Yuanjun, Zhang Baowen, Wang Xuesong
机构信息
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.
出版信息
Chem Commun (Camb). 2014 Jun 21;50(49):6520-2. doi: 10.1039/c4cc01471e. Epub 2014 May 13.
PMID:24820402
Abstract
The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.
摘要
发现五齿配体（N4Py）中的一个吡啶从钴中心解离是形成氢化钴（III）物种的原因，氢化钴（III）物种是光催化质子还原不可或缺的中间体。
Zotero 插件