6-O-三苯甲基-α-D-吡喃葡萄糖苷甲醇溶剂化物
Methyl 6-O-trityl-α-d-gluco-pyran-oside methanol disolvate.
作者信息
Gültekin Zeynep, Civan Mehmet, Frey Wolfgang, Hökelek Tuncer
机构信息
Department of Chemistry, Çankırı Karatekin University, TR-18100, Çankırı, Turkey.
Department of Physics, Hacettepe University, 06800 Beytepe, Ankara, Turkey.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 29;70(Pt 4):o492-3. doi: 10.1107/S1600536814006461. eCollection 2014 Apr 1.
The asymmetric unit of the title compound, C26H28O6·2CH3OH, contains two independent methyl 6-O-trityl-α-d-gluco-pyran-oside mol-ecules and four methanol solvent mol-ecules. The rings of two methyl α-d-gluco-pyran-oside adopt chair conformations. In the crystal, extensive intra- and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular architecture.
标题化合物C26H28O6·2CH3OH的不对称单元包含两个独立的甲基6-O-三苯甲基-α-D-吡喃葡萄糖苷分子和四个甲醇溶剂分子。两个甲基α-D-吡喃葡萄糖苷的环呈椅式构象。在晶体中，广泛的分子内和分子间O-H⋯O和C-H⋯O氢键将分子连接成三维超分子结构。
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