Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL33620, USA.
Chem Soc Rev. 2014 Aug 21;43(16):5444-55. doi: 10.1039/c4cs00075g.
This tutorial review details the emergence of template-directed synthesis of metal-organic materials (MOMs) with emphasis upon reports of MOMs in which the template is retained, template@MOMs, and structurally characterized. Such MOMs enable analysis of the nature of the intermolecular interactions that occur between the template and the resulting host framework. The utilization of such understanding can enable template-directed synthesis to serve as a crystal engineering tool for the preparation of new MOMs, especially those that cannot be accessed without the use of a template. We anticipate that this review will guide future research by delineating several rules for identifying appropriate templates and molecular building blocks to afford MOMs with targeted structures and properties.
本教程详细回顾了模板指导的金属有机材料（MOMs）合成的出现，重点介绍了模板保留的 MOMs 报告，即模板@MOMs，并对其进行了结构表征。此类 MOMs 使人们能够分析模板与所得主体骨架之间发生的分子间相互作用的性质。利用这种理解，可以使模板指导的合成成为制备新型 MOMs 的晶体工程工具，特别是那些如果不使用模板就无法获得的 MOMs。我们预计，通过阐明确定合适模板和分子构建块的几个规则，本综述将为未来的研究提供指导，以获得具有目标结构和性能的 MOMs。
