Seinberg Liis, Yamamoto Shinpei, Tsujimoto Masahiko, Kobayashi Yoji, Takano Mikio, Kageyama Hiroshi
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510, Japan.
Chem Commun (Camb). 2014 Jul 4;50(52):6866-8. doi: 10.1039/c4cc01592d.
We studied synthesis of Ni or Fe nanoparticle-loaded multiwalled carbon nanotubes (MWCNTs) by pyrolyzing metal organic salts with CaH2, a very strong reductant. The use of CaH2 lowered the formation temperature of MWCNTs down to 400 °C without the use of toxic halogen-containing precursors and assistance of plasma.
我们研究了通过用非常强的还原剂氢化钙热解金属有机盐来合成负载镍或铁纳米颗粒的多壁碳纳米管(MWCNT)。氢化钙的使用将多壁碳纳米管的形成温度降低至400℃,无需使用有毒的含卤素前驱体和等离子体辅助。