通过三联吡啶配体与 Ru(II) 的一锅反应构建高度对称的纳米球。
Construction of a highly symmetric nanosphere via a one-pot reaction of a tristerpyridine ligand with Ru(II).
机构信息
Department of Polymer Science and ‡Department of Chemistry, The University of Akron , Akron, Ohio 44325, United States.
出版信息
J Am Chem Soc. 2014 Jun 11;136(23):8165-8. doi: 10.1021/ja502962j. Epub 2014 May 22.
PMID:24840764
Abstract
A three-dimensional, highly symmetric, terpyridine-based, spherical complex was synthesized via the coordination of four novel, trisdentate ligands and six Ru(2+) ions, and it exhibits excellent stability over a wide range of pH values (1-14). Structural confirmation was obtained by NMR and ESI-TWIM-MS.
摘要
通过四个新型的、三齿配体和六个 Ru(2+) 离子的配位，合成了一种具有三维、高度对称、基于三吡啶的球形配合物，它在很宽的 pH 值范围内（1-14）具有优异的稳定性。通过 NMR 和 ESI-TWIM-MS 得到了结构确证。
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