1,4-二氮杂双环[2.2.2]辛烷介导的基于异腈的多组分反应：高度取代环戊烯的合成
DABCO-mediated isocyanide-based multicomponent reaction: synthesis of highly substituted cyclopentenes.
作者信息
Wen Li-Rong, Lan Ming-Chao, Yuan Wen-Kui, Li Ming
机构信息
State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China.
出版信息
Org Biomol Chem. 2014 Jul 14;12(26):4628-32. doi: 10.1039/c4ob00012a.
PMID:24848701
Abstract
Highly substituted cyclopentenes can be accessed rapidly from isocyanides, aldehydes and malononitrile or ethyl cyanoacetate (AB2C2) using DABCO as a catalyst under solvent-free conditions at 40 °C within 30 min.
摘要
在无溶剂条件下，以三乙烯二胺（DABCO）为催化剂，于40℃反应30分钟，可从异腈、醛和丙二腈或氰基乙酸乙酯（AB2C2）快速制得高度取代的环戊烯。
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