Krylova Valentina A, Djurovich Peter I, Conley Brian L, Haiges Ralf, Whited Matthew T, Williams Travis J, Thompson Mark E
Department of Chemistry, University of Southern California, Los Angeles 90089-0744, USA.
Chem Commun (Camb). 2014 Jul 11;50(54):7176-9. doi: 10.1039/c4cc02037e.
A series of three phosphorescent mononuclear (NHC)-Cu(I) complexes were prepared and characterized. Photophysical properties were found to be largely controlled by the NHC ligand chromophore. Variation of the NHC ligand leads to emission colour tuning over 200 nm range from blue to red, and emission efficiencies of 0.16-0.80 in the solid state.
制备并表征了一系列三种磷光单核（NHC）-Cu（I）配合物。发现光物理性质在很大程度上受NHC配体发色团控制。NHC配体的变化导致发射颜色在200nm范围内从蓝色调至红色，并且固态下的发射效率为0.16 - 0.80。
