杂芳族化合物脱芳构化的最新进展。
Recent advances in dearomatization of heteroaromatic compounds.
作者信息
Ding Qiuping, Zhou Xiaoli, Fan Renhua
机构信息
Key Laboratory of Small Functional Organic Molecule, Ministry of Education and Jiangxi's Key Laboratory of Green Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330022, China.
出版信息
Org Biomol Chem. 2014 Jul 21;12(27):4807-15. doi: 10.1039/c4ob00371c.
Dearomatization reactions provide the most efficient method for the synthesis of spiro- or fused-ring systems from readily available compounds. This review summarizes the recent developments in dearomatization reactions of indoles, pyridines, quinolines, isoquinolines, and some other heteroaromatic compounds. The applications of these methods in total synthesis of natural products are also briefly introduced.
脱芳构化反应为从易得的化合物合成螺环或稠环体系提供了最有效的方法。本综述总结了吲哚、吡啶、喹啉、异喹啉及其他一些杂芳族化合物脱芳构化反应的最新进展。还简要介绍了这些方法在天然产物全合成中的应用。
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