School of Biotechnology and Food Engineering, Hefei University of Technology, Hefei, 230009 China.
J Food Sci Technol. 2014 Jun;51(6):1213-7. doi: 10.1007/s13197-012-0625-z. Epub 2012 Jan 31.
Carbon monoxide (CO), L-cysteine and L-histidine were tested to coordinate with hemin chloride (pigment containing haem iron). In the presence of sodium dithionite, both CO and L-cysteine could react with hemin to afford respectively the corresponding complexes: CO-hemin and L-cysteine hemin; while L-histidine could not react with hemin. Both CO-hemin and L-cysteine hemin could decompose and release the corresponding ligand to generate hemin. Both light and temperature had an obvious effect on stabilization of these complexes. By sensory evaluation, both CO-hemin and L-cysteine hemin have bright red colour and show a potential as cured cooked-meat pigments (CCMP) in the manufacture of meat product.
一氧化碳(CO)、L-半胱氨酸和 L-组氨酸被测试与氯化血晶素(含有血红素铁的色素)配位。在连二亚硫酸钠的存在下,CO 和 L-半胱氨酸都能与血晶素反应,分别得到相应的配合物:CO-血晶素和 L-半胱氨酸血晶素;而 L-组氨酸不能与血晶素反应。CO-血晶素和 L-半胱氨酸血晶素都可以分解并释放相应的配体生成血晶素。光和温度都对这些配合物的稳定性有明显的影响。通过感官评价,CO-血晶素和 L-半胱氨酸血晶素都具有鲜艳的红色,并在肉类产品的生产中显示出作为发色熟肉色素(CCMP)的潜力。