Xu Peng, Hao Qing-Ju, Ji Dong-Sheng, Zhang Jun-Ke, Liu Zi-Rui, Hu Bo, Wang Yue-Si, Jiang Chang-Sheng
Huan Jing Ke Xue. 2014 Mar;35(3):820-9.
To study the characteristics of atmospheric pollutants in the urban area of Beibei district of Chongqing, the concentrations of the atmospheric pollutants were measured by automatic on-line continuous monitoring equipments from Jan. 2012 to Feb. 2013. The results showed that the concentrations of the pollutants often exceeded the corresponding values of the new National Ambient Air Quality Standards (GB 3095-2012) except SO2. Of these pollutants, PM2.5 was the most serious in this area. The concentrations of the atmospheric pollutants had significant seasonal variation. The concentrations of O3 and O(x) were both the highest in summer and the lowest in winter. The average concentrations of O3 were (36.1 +/- 19.2), (48.8 +/- 32.6), (29.8 +/- 28.6) and (18.2 +/- 15.8) microg x m(-3), and the average O(x) concentrations were (77.6 +/- 20.6), (91.3 +/- 37.6), (77.5 +/- 30.6) and (69.4 +/- 18.2) microg x m(-3) in spring, summer, autumn and winter in 2012, respectively. The concentrations of NO(x) appeared higher in winter and lower in summer, the average concentrations of NO, NO2 and NO(x) were (11.8 +/- 9.4), (42.3 +/- 13.1) and (54.1 +/- 20.8) microg x m(-3) in spring, (8.2 +/- 4.9), (40.5 +/- 9.9) and (48.7 +/- 12.6) microg x m(-3) in summer, (20.7 +/-17.1), (47.2 +/- 14.1) and (67.9 +/- 25.5) microg x m(-3) in autumn, and (30.4 +/- 25.1), (51.2 +/- 15.9), (81.6 +/- 37.9) microg x m(-3) in winter. The concentrations of SO2 appeared higher in spring and winter, and lower in summer and autumn. The concentrations of SO2 were (50.5 +/- 23.3), (26.3 +/- 16.7), (38.8 +/- 18.4) and (53.7 +/- 23.4) microg x m(-3) in spring, summer, autumn and winter, respectively. The concentrations of PM2.5 appeared higher in winter and changed smoothly in other seasons, with the average concentration of (61.4 +/- 28.5), (68.1 +/- 32.5), (61.9 +/- 27.1) and (89.6 +/- 44.2) microg x m(-3) in spring, summer, autumn and winter, respectively. The curves of diurnal variations of O3, O(x), NO, NO(x) and SO2 all showed single peak. However, the time of the peak values varied for different pollutants, 16:00 for O3 and O(x), and 8:00-11:00 for NO, NO(x) and SO2. The diurnal variations of NO2 and PM2.5 were similar to the two peaks that appeared in the morning and at night, respectively. Moreover, the diurnal ranges of O3 and O(x) concentrations were much wider in summer, while the wider ranges were observed in winter for NO, NO2, NO(x), SO2 and PM2.5. There was no difference in the diurnal pattern of NO between weekends and weekdays, the concentrations of N2O in weekdays were much higher than those on weekends, but with O3 the situation was the opposite. Correlation analysis indicated that the O3 concentration was positively correlated with temperature and wind speed, while negatively correlated with relative humidity. However, the situation of NO(x) was the opposite. PM2.5 concentration was negatively correlated with temperature and wind speed, while positively correlated with relative humidity. SO2 concentration had different correlations with the meteorological parameters in different seasons. In addition, wind direction was an important factor affecting the concentrations of the atmospheric pollutants.
为研究重庆市北碚区城区大气污染物特征,于2012年1月至2013年2月采用自动在线连续监测设备对大气污染物浓度进行了测定。结果表明,除二氧化硫外,其他污染物浓度常超过新的《环境空气质量标准》(GB 3095—2012)相应值。其中,该地区PM2.5污染最为严重。大气污染物浓度具有明显的季节变化特征。O3和O(x)浓度均夏季最高、冬季最低。2012年春、夏、秋、冬四季O3平均浓度分别为(36.1±19.2)、(48.8±32.6)、(29.8±28.6)和(18.2±15.8)μg·m-3,O(x)平均浓度分别为(77.6±20.6)、(91.3±37.6)、(77.5±30.6)和(69.4±18.2)μg·m-3。NO(x)浓度冬季较高、夏季较低,2012年春、夏、秋、冬四季NO、NO2和NO(x)平均浓度分别为(11.8±9.4)、(42.3±13.1)和(54.1±20.8)μg·m-3、(8.2±4.9)、(40.5±9.9)和(48.7±12.6)μg·m-3、(20.7±17.1)、(47.2±14.1)和(67.9±25.5)μg·m-3、(30.4±25.1)、(51.2±15.9)、(81.6±37.9)μg·m-3。SO2浓度春、冬季较高,夏、秋季较低,春、夏、秋、冬四季SO2浓度分别为(50.5±23.3)、(26.3±16.7)、(38.8±18.4)和(53.7±23.4)μg·m-3。PM2.5浓度冬季较高,其他季节变化较平缓,春、夏、秋、冬四季平均浓度分别为(61.4±28.5)、(68.1±32.5)、(61.9±27.1)和(89.6±44.2)μg·m-3。O3、O(x)、NO、NO(x)和SO2的日变化曲线均呈单峰型,但不同污染物峰值出现时间不同,O3和O(x)为16:00,NO、NO(x)和SO2为8:00—11:00。NO2和PM2.5的日变化分别在早晚出现双峰。此外,O3和O(x)浓度日变化幅度夏季较大,NO、NO2、NO(x)、SO2和PM2.5日变化幅度冬季较大。周末与工作日NO日变化规律无差异,工作日N2O浓度明显高于周末,而O3则相反。相关性分析表明,O3浓度与气温、风速呈正相关,与相对湿度呈负相关;NO(x)则相反。PM2.5浓度与气温、风速呈负相关,与相对湿度呈正相关。SO2浓度与气象参数的相关性在不同季节有所不同。此外,风向是影响大气污染物浓度的重要因素。