Yamamoto T, Nakabayashi N
Shika Zairyo Kikai. 1989 Nov;8(6):908-12.
MMA grafted silk fibers were prepared by graft polymerization initiated by TBB, as a collagen model. The loop strength of the fiber was measured to investigate the relationship between grafting and the adhesion of resin to dentin. The loop strength of the grafted fiber decreased with increases in the degree of grafting since the crystal structure of the silk was destroyed by the process. As for adhesion of resin to dentin by graft polymerization of MMA onto collagen, graft polymerization strongly influences the tensile bond strength of the resin to dentin because of weakening of the collagen.
以TBB引发的接枝聚合反应制备了甲基丙烯酸甲酯(MMA)接枝的丝纤维,作为一种胶原模型。通过测量纤维的环强度来研究接枝与树脂对牙本质黏附之间的关系。由于丝的晶体结构在此过程中被破坏,接枝纤维的环强度随着接枝度的增加而降低。至于通过MMA在胶原上的接枝聚合使树脂与牙本质黏附,接枝聚合由于使胶原弱化而强烈影响树脂与牙本质的拉伸粘结强度。