混合金钯多氧代贵金属酸盐[NaAu(III)₄Pd(II)₈O₈(AsO₄)₈](11⁻)
The mixed gold-palladium polyoxo-noble-metalate [NaAu(III)4Pd(II)8O8(AsO4)8](11-).
作者信息
Izarova Natalya V, Kondinski Aleksandar, Vankova Nina, Heine Thomas, Jäger Patrick, Schinle Florian, Hampe Oliver, Kortz Ulrich
机构信息
Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229; Current address: Peter-Grünberg-Institut, PGI-6, Forschungszentrum Jülich, 52425 Jülich (Germany), On leave from Nikolaev Institute of Inorganic Chemistry, Prospekt Lavrentyeva 3, 630090 Novosibirsk (Russia).
出版信息
Chemistry. 2014 Jul 7;20(28):8556-60. doi: 10.1002/chem.201403032. Epub 2014 Jun 4.
The first fully inorganic, discrete gold-palladium-oxo complex NaAu(III) 4 Pd(II) 8 O8 (AsO4 )8 has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.
首个完全无机的离散型金 - 钯 - 氧配合物NaAu(III)₄Pd(II)₈O₈(AsO₄)₈已在水介质中合成。单晶X射线衍射、元素分析、质谱分析和密度泛函理论计算相结合，确定了这种新型聚阴离子的结构和组成，紫外/可见光谱研究表明它在中性水介质中是稳定的。
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