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杂原子桥联四苯:合成、结构和性质。

Heteroatom-bridged tetraphenylenes: synthesis, structures, and properties.

机构信息

Department of Chemistry, State Key Laboratory of Synthetic Chemistry, Center of Novel Functional Molecules and Institute of Molecular Functional Materials, The Chinese University of Hong Kong , Shatin, New Territories, Hong Kong SAR, China.

出版信息

Org Lett. 2014 Jun 20;16(12):3252-5. doi: 10.1021/ol501267z. Epub 2014 Jun 9.

DOI:10.1021/ol501267z
PMID:24909846
Abstract

Novel oxygen-, nitrogen-, sulfur-, and selenium-bridged tetraphenylenes were prepared from known tetraphenylene derivatives. Structures of these compounds were unambiguously confirmed by X-ray crystallographic analyses. Photophysical and electrochemical investigations of these heteroatom-bridged tetraphenylenes suggested their potential applications as electronic materials.

摘要

新型含氧、氮、硫和硒桥联四苯通过已知的四苯衍生物制备得到。这些化合物的结构通过 X 射线晶体学分析得到了明确的证实。对这些杂原子桥联四苯的光物理和电化学研究表明,它们有可能作为电子材料得到应用。

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