Wolska J M, Pociecha D, Mieczkowski J, Górecka E
Department of Chemistry, Warsaw University, Pasteura 1, 02-093 Warsaw, Poland.
Chem Commun (Camb). 2014 Jul 28;50(59):7975-8. doi: 10.1039/c4cc02242d.
New hybrid materials made of gold nanoparticles functionalized by mesogenic ligands form laminated smectic phases. Mechanical shearing produces macro size domains with uniformly oriented layers with the layer normal either perpendicular (perpendicular mode) or parallel (transverse mode) to the shearing direction. This is in contrast to low weight and polymer liquid crystals which usually show parallel mode of orientation.
由介晶配体功能化的金纳米颗粒制成的新型杂化材料形成层状近晶相。机械剪切产生宏观尺寸的畴，其层均匀取向，层法线垂直（垂直模式）或平行（横向模式）于剪切方向。这与通常呈现平行取向模式的低分子量聚合物液晶形成对比。
