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溶解于水性缓冲溶液中的含吡啶基烷基胺配体的铜配合物对氧气的电化学还原：活性与氧化还原电位之间的关系。

Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential.

作者信息

Asahi Masafumi, Yamazaki Shin-ichi, Itoh Shinobu, Ioroi Tsutomu

机构信息

Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, 1-8-31, Midorigaoka, Ikeda, Osaka 563-8577, Japan.

出版信息

Dalton Trans. 2014 Jul 28;43(28):10705-9. doi: 10.1039/c4dt00606b.

DOI:10.1039/c4dt00606b
PMID:24926744
Abstract

The Cu(II)/Cu(I) redox properties and electrochemical O2 reduction activity of a series of Cu(II)-complexes with pyridylalkylamine ligands were investigated in a neutral buffer solution. The relationship between Cu(II)/Cu(I) redox properties and O2 reduction activity was clearly demonstrated by voltammetric analyses.

摘要

在中性缓冲溶液中研究了一系列含有吡啶基烷基胺配体的Cu(II)配合物的Cu(II)/Cu(I)氧化还原性质和电化学氧还原活性。通过伏安分析清楚地证明了Cu(II)/Cu(I)氧化还原性质与氧还原活性之间的关系。

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