School of Mechanical and Manufacturing Engineering, the University of New South Wales , Sydney, New South Wales 2052, Australia.
Environ Sci Technol. 2014 Jul 15;48(14):8243-50. doi: 10.1021/es500661w. Epub 2014 Jun 20.
The current understanding of soot particle morphology in diesel engines and their dependency on the fuel injection timing and pressure is limited to those sampled from the exhaust. In this study, a thermophoretic sampling and subsequent transmission electron microscope imaging were applied to the in-flame soot particles inside the cylinder of a working diesel engine for various fuel injection timings and pressures. The results show that the number count of soot particles per image decreases by more than 80% when the injection timing is retarded from -12 to -2 crank angle degrees after the top dead center. The late injection also results in over 90% reduction of the projection area of soot particles on the TEM image and the size of soot aggregates also become smaller. The primary particle size, however, is found to be insensitive to the variations in fuel injection timing. For injection pressure variations, both the size of primary particles and soot aggregates are found to decrease with increasing injection pressure, demonstrating the benefits of high injection velocity and momentum. Detailed analysis shows that the number count of soot particles per image increases with increasing injection pressure up to 130 MPa, primarily due to the increased small particle aggregates that are less than 40 nm in the radius of gyration. The fractal dimension shows an overall decrease with the increasing injection pressure. However, there is a case that the fractal dimension shows an unexpected increase between 100 and 130 MPa injection pressure. It is because the small aggregates with more compact and agglomerated structures outnumber the large aggregates with more stretched chain-like structures.
目前,人们对柴油机中烟灰颗粒形态及其对喷油正时和压力的依赖性的认识仅限于从排气中采样得到的结果。在这项研究中,采用了热敏采样和随后的透射电子显微镜成像技术,对工作中的柴油机气缸内的燃烧室内烟灰颗粒进行了各种喷油正时和压力的研究。结果表明,当喷油正时从上止点后延迟到-12 到-2 曲轴角度时,每个图像的烟灰颗粒数量减少了 80%以上。延迟喷油还导致烟灰颗粒在 TEM 图像上的投影面积减少了 90%以上,烟灰团聚体的尺寸也变小了。然而,发现初级颗粒的大小对喷油正时的变化不敏感。对于喷油压力的变化,发现初级颗粒和烟灰团聚体的大小都随喷油压力的增加而减小,这表明高喷油速度和动量的优势。详细分析表明,每个图像的烟灰颗粒数量随喷油压力的增加而增加,最高可达 130 MPa,主要是由于较小的颗粒团聚体增加,其旋转半径小于 40nm。分形维数随喷油压力的增加而总体减小。然而,在 100 到 130 MPa 喷油压力之间,分形维数出现了一个意外的增加。这是因为具有更紧凑和团聚结构的小团聚体数量超过了具有更伸展链状结构的大团聚体数量。